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Copper-catalyzed C-O bond formation: an efficient one-pot highly regioselective synthesis of furans from (2-furyl)carbene complexes.

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WOS被引频次:80
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成果类型:
期刊论文
作者:
Hua Cao;Haiying Zhan;Jinghe Cen;Jingxin Lin;Yuanguang Lin;Qiuxia Zhu;Minling Fu;Huanfeng Jiang
通讯作者:
Cao, Hua
作者机构:
[Huanfeng Jiang] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China.
[Yuanguang Lin; Jingxin Lin; Minling Fu; Haiying Zhan; Qiuxia Zhu; Jinghe Cen; Hua Cao] Guangdong Pharmaceut Univ, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China.
通讯机构:
[Cao, Hua] Guangdong Pharmaceut Univ, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China.
语种:
英文
期刊:
ORGANIC LETTERS
ISSN:
1523-7060
年:
2013
卷:
15
期:
5
页码:
1080-1083
文献类别:
WOS:Article
所属学科:
ESI学科类别:化学;WOS学科类别:Chemistry, Organic
入藏号:
WOS:000315707400027;PMID:23413974
基金类别:
Foundation for National Natural Science; Foundation of China [20932002, 21172076]; National Basic Research Program of China (973 Program) [2011CB808600]; Ministry of Education of China [20090172110014]; Guangdong Natural Science Foundation [10351064101000000]; Distinguished Young Talentsin Higher Education of Guangdong, China [LYM11083]
机构署名:
本校为第一且通讯机构
院系归属:
医药化工学院
摘要:
A convenient one-pot Cu(I)-catalyzed strategy for regioselective synthesis of trisubstituted furan derivatives has been developed via (2-furyl) carbene complexes. This process has opened a new synthetic route to a variety of alpha-carbonyl furans using air as the oxidant affording furans in good yields.
参考文献:
Barluenga J, 2004, J AM CHEM SOC, V126, P5974, DOI 10.1021/ja049200r
Barluenga J, 1999, J AM CHEM SOC, V121, P4516, DOI 10.1021/ja9825736
Barluenga J, 2008, J AM CHEM SOC, V130, P13528, DOI 10.1021/ja8058342
Barluenga J, 2007, J AM CHEM SOC, V129, P14422, DOI 10.1021/ja075106+
Bechem B, 2010, J ORG CHEM, V75, P1795, DOI 10.1021/jo902697g

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